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Fluid Handling for
Liquid Chromatography

Pump selection for autosampler metering, needle washing, waste removal and method-specific post-column reagent dosing.

Key Fluidic Tasks

  • Sample aspiration and metering
  • Reagent delivery and path switching
  • Rinsing, drainage and waste handling
  • Pressure, liquid-level and bubble monitoring
Home/Applications/Analytical Instruments
  • Chromatography / Autosampler
  • Spectroscopy / Elemental Analysis
  • Water Quality / Environmental Monitoring
  • Sample Preparation Systems
  • Laboratory Analyzer System Integration

Valveless Metering Pumps for LC Post-Column Derivatization

Liquid chromatography · Post-column derivatization

Some LC methods introduce a derivatization reagent after the column and before detection. The pump continuously meters an auxiliary reagent, rather than supplying the mobile phase through the separation column. RPL single-head valveless pumps can be evaluated as engineering candidates; suitability depends on the reagent, backpressure, flow variation and complete analytical method.

Application guides

Liquid chromatography

Liquid chromatography
Piston pumps in LC autosamplers
Sample aspiration and injection meteringSample transfer and loop loading
Diaphragm pumps for needle wash and waste
Needle-wash liquid supplyWash-station waste aspiration
Valveless pumps for post-column derivatization
Continuous derivatization-reagent dosing

ON THIS PAGE

Keep the reagent pump on a separate branchShortlist by displacement, speed and method demandValidate the method, not just the pump's average outputAdd a reagent branch only when the detection method needs itUnderstand what valveless construction changesQuestions before selecting an RPL configurationReferencesRelated guides

01Keep the reagent pump on a separate branch

Column effluent→Mixing junction→Reaction tubing→Detector
Separated analytes follow the main post-column path
Derivatization-reagent reservoir→Candidate RPL metering pump→Mixing junction
The reagent branch joins at the mixing junction above

Column effluent does not pass through the RPL reagent pump in this arrangement. Post-column derivatization adds and reacts reagent with separated components before detection; the method determines whether this additional branch is needed.[1]

02Shortlist by displacement, speed and method demand

Displacement per revolution is not flow per minute[2][3][4]
SeriesPublished displacement rangeWhen to evaluate
RPL-P412–80 µL/revAn initial candidate when a smaller displacement is useful for the required reagent flow
RPL-P6.3550–300 µL/revA candidate where mechanical displacement adjustment and speed can provide the required operating range
RPL-P15300–1,200 µL/revOnly where the method requires substantially more reagent; not a default low-flow LC selection

The range is neither a minimum reliable dose nor a guaranteed continuous-flow range. Confirm the permitted speed, displacement setting, duty and installed load. A larger RPL model is not included simply because it belongs to the same family.

  • RPL-P4 valveless metering pump
  • RPL-P6.35 valveless metering pump

The RPL selection guide covers displacement and configuration choices for the separate reagent branch. Use it to prepare an engineering shortlist, not as evidence that a model is validated for every derivatization method.

03Validate the method, not just the pump's average output

  • Match reagent flow to column effluent, reaction chemistry and permitted dilution.
  • Check mixing uniformity while controlling added volume and peak broadening.
  • Evaluate whether output variation, speed changes or backpressure changes create unacceptable baseline noise.
  • Use reagent composition, precipitation risk and cleaning procedure to assess every wetted material.

These checks establish an application candidate, not a prequalified reagent-pump replacement for every LC method. Obtain performance data at the intended working point before fixing the configuration.

04Add a reagent branch only when the detection method needs it

A method that detects the separated compounds without a post-column reaction does not need this pump branch. When derivatization is required, define reagent concentration and flow, mixing geometry, reaction conditions and detector acceptance first.

  • Continuous derivatization-reagent dosing

05Understand what valveless construction changes

RPL metering combines rotating and reciprocating ceramic-piston motion to organize inlet and outlet transfer without conventional dynamic check valves inside the pump. Displacement per revolution and rotational speed provide the basis for a metering configuration.[3]

Valveless does not mean instantaneous pulse-free delivery, nor does it remove the system's need for shutoff, source selection or anti-siphon measures. Check the detector baseline and standards as well as liquid collected over time.

Review the valveless metering-pump principle to understand the pumping mechanism and its boundaries. Valveless operation does not remove the need to measure flow variation, compatibility or detector response.

06Questions before selecting an RPL configuration

Can an RPL candidate replace the high-pressure LC main pump?

That is not the use described here. The candidate serves a post-column reagent branch. Main mobile-phase delivery requires its own validated high-pressure, continuous-flow and gradient capabilities.

Is a displacement range sufficient to select the model?

No. You also need speed range, continuous-duty capability, actual backpressure, wetted materials, control and allowable flow fluctuation. A value in µL/rev cannot be compared directly with a target in mL/min.

What remains unconfirmed without method data?

The final pump configuration, reagent compatibility, low-flow stability, baseline contribution and maintenance interval. Treat the shortlist as an engineering evaluation until these are established.

  • Discuss your LC fluid-path requirements

References

View references (4)
  1. [1]Shimadzu: Analytical Methods for Amino Acids — post-column derivatization
  2. [2]FOREACH RPL-P4: displacement and configuration
  3. [3]FOREACH RPL-P6.35: displacement and configuration
  4. [4]FOREACH RPL-P15: displacement and configuration

Related guides

  • Liquid chromatography fluid-handling overview
  • Continuous derivatization-reagent dosing

Related Products

RPL-P4 valveless metering pump — representative configuration; select capacity and materials on the product page

RPL-P4 valveless metering pump

RPL-P6.35 valveless metering pump — representative configuration; select capacity and materials on the product page

RPL-P6.35 valveless metering pump

Related Technical Articles

Valveless Metering Pump Selection Guide: FOREACH Models and Applications

To select a valveless metering pump, first define the volume per dose and the time available for dispensing. Then check displacement per revolution, drive speed, wetted materials, backpressure and connections, and verify delivery in the actual fluid path. Neither flow rate alone nor the label ‘metering pump’ is enough to select a model.

2026-09-16View Details

What Is a Valveless Metering Pump? Working Principle, Applications and Selection

A valveless metering pump is a positive-displacement pump that combines rotary and axial reciprocating piston motion to switch the fluid path, draw liquid in and discharge it. Its pumping mechanism does not rely on conventional inlet and outlet check valves. It can serve reagent dispensing, titration, filling and two-fluid proportional delivery, but metering performance still has to be verified with the actual fluid, pressure, tubing, drive and cleaning conditions.

2026-09-21View Details

Discuss your liquid chromatography fluid path

Share the liquid, required dose or flow, pressure in each operating state, cycle time and acceptance criteria so we can evaluate a suitable configuration.

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